An "off-axis" Mn-Mn bond in Mn2(CO)10 at high pressure.
نویسندگان
چکیده
At variance with what was previously reported, Mn2(CO)10 does not transform its conformation from staggered to eclipsed in the high pressure crystal form. X-ray powder diffraction, DFT calculations and Raman spectroscopy show that the staggered conformation is retained. Instead, a rotation and a translation of the Mn(CO)5 pyramidal units produce an "off-axis" and rather shorter Mn-Mn bond.
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عنوان ژورنال:
- Chemical communications
دوره 50 85 شماره
صفحات -
تاریخ انتشار 2014